Flavoenzyme‐mediated Regioselective Aromatic Hydroxylation with Coenzyme Biomimetics
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چکیده
منابع مشابه
How does the axial ligand of cytochrome P450 biomimetics influence the regioselectivity of aliphatic versus aromatic hydroxylation?
The catalytic activity of high-valent iron-oxo active species of heme enzymes is known to be dependent on the nature of the axial ligand trans to the iron-oxo group. In a similar fashion, experimental studies on iron-oxo porphyrin biomimetic systems have shown a significant axial ligand effect on ethylbenzene hydroxylation, with an axial acetonitrile ligand leading to phenyl hydroxylation produ...
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ژورنال
عنوان ژورنال: ChemCatChem
سال: 2020
ISSN: 1867-3880,1867-3899
DOI: 10.1002/cctc.201902044